# Scope and Language of Thermodynamics

This chapter is from the book

## 1.4 Units

Throughout this book we will use primarily the SI system of units with occasional use of the American Engineering system. The main quantities of interests are pressure, temperature, and energy. These are briefly reviewed below. Various physical constants that are commonly used in thermodynamics are shown in Table 1-1.

#### Table 1-1: Thermodynamic constants

 Avogadro's number NA = 6.022 × 1023 mol−1 Boltzmann's constant kB = 1.38 × 10−23 J/K Ideal-gas constant R = kBNA = 8.314 J/mol K Absolute zero 0 K = 0 R = −273.15 °C= −459.67 °F

#### Pressure

Pressure is the ratio of the force acting normal to a surface, divided by the area of the surface. In thermodynamics, pressure generates the forces that give rise to mechanical work. The SI unit of pressure is the pascal, Pa, and is defined as the pressure generated by 1 N (newton) acting on a 1 m2 area:

The last equality in the far right is obtained by writing J = N · m. The pascal is an impractically small unit of pressure because 1 N is a small force and 1 m2 is a large area. A commonly used multiple of Pa is the bar:

An older unit of pressure, still in use, is the Torr, or mm Hg, representing the hydrostatic pressure exerted by a column of mercury 1 mm high. In the American Engineering system of units, pressure is measured in pounds of force per square inch, or psi. The relationship between the various units can be expressed through their relationship to the standard atmospheric pressure:

#### Temperature

Temperature is a fundamental property in thermodynamics. It is a measure of the kinetic energy of molecules and gives rise the sensation of “hot” and “cold.” It is measured using a thermometer, a device that obtains temperature indirectly by measuring some property that is a sensitive function of temperature, for example, the volume of mercury inside a capillary (mercury thermometer), the electric current between two different metallic wires (thermocouple), etc. In the SI system, the absolute temperature is a fundamental quantity (dimension) and its unit is the kelvin (K). In the American Engineering system, absolute temperature is measured in rankine (R), whose relationship to the kelvin is,

Temperatures measured in absolute units are always positive. The absolute zero is a special temperature that cannot be reached except in a limiting sense.

In practice, temperature is usually measured in empirical scales that were originally developed before the precise notion of temperature was clear. The two most widely used are the Celsius scale and the Fahrenheit. They are related to each other and to the absolute scales as follows:4

where the subscript in T indicates the corresponding units. The units of absolute temperature are indicated without the degree (°) symbol, for example, K or R; the units in the Celsius and Fahrenheit scales include the degree (°) symbol, for example, °C, °F. Although temperatures are almost always measured in the empirical scales Celsius or Fahrenheit, it is the absolute temperature that must be used in all thermodynamics equations.

#### Mole (mol, gmol, lb-mol)

The mole5 is a defined unit in the SI system such that 1 mol is an amount of matter that contains exactly NA molecules, where NA = 6.022 × 1023 mol−1 is Avogadro’s number.6 The mass of 1 mol is the molar mass and is numerically equal to the molecular weight multiplied by 10−3kg. For example, the molar mass of water (molecular weight 18.015) is

The symbol Mm will be used to indicate the molar mass. The number of moles n that correspond to mass m is

The pound-mol (lb-mol) is the analogous unit in the American Engineering system and represents an amount of matter equal to the molecular weight expressed in lbm. The relationship between the mol and lb-mol is

#### Energy

The SI unit of energy is the joule, defined as the work done by a force 1 N over a distance of 1 m, also equal to the kinetic energy of a mass 1 kg with velocity 1m/s:

The kJ (1 kJ = 1000 J) is a commonly used multiple.

As a form of energy, heat does not require its own units. Nonetheless, units specific to heat remain in wide use today, even though they are redundant and require additional conversions when the calculation involves both heat and work. These units are the cal (calorie) and the Btu (British thermal unit) and are related to the joule through the following relationships:

Some unit conversions encountered in thermodynamics are shown in Table 1-2.

#### Table 1-2: Common units and conversion factors

 Magnitude Definition Units Other Units and Multiples Length - m 1 cm = 10-2 m 1 ft = 0.3048 m 1 in = 2.54 × 10-2 m Mass - kg 1 g = 10-3 kg 1 lb = 0.4536 kg Time - s 1 min = 60 s 1 hr = 3600 s Volume (length)3 m3 1 cm3 = 10-6 m3 1 L = 10-3 m3 Force (mass)×(acceleration) N = kg m s-2 1 lbf = 4.4482 N Pressure (force)/(area) = (energy)/(volume) Pa = N m-2 1 Pa = 10-3 kJ/m3 1 bar = 105 Pa 1 psi = 0.06895 bar Energy (force)×(length) = (mass)×(velocity)2 J = kg m2 s-2 1 kJ = 103 J 1 Btu = 1.055 kJ Specific energy (energy)/(mass) J/kg 1 kJ/kg=2.3237 kJ/kg 1 Btu/lbm=2.3237 kJ/kg Power (energy)/(time) W = J/s 1 Btu/s = 1.055 kW 1 hp = 735.49 W

### InformIT Promotional Mailings & Special Offers

I would like to receive exclusive offers and hear about products from InformIT and its family of brands. I can unsubscribe at any time.

## Overview

Pearson Education, Inc., 221 River Street, Hoboken, New Jersey 07030, (Pearson) presents this site to provide information about products and services that can be purchased through this site.

This privacy notice provides an overview of our commitment to privacy and describes how we collect, protect, use and share personal information collected through this site. Please note that other Pearson websites and online products and services have their own separate privacy policies.

## Collection and Use of Information

To conduct business and deliver products and services, Pearson collects and uses personal information in several ways in connection with this site, including:

### Questions and Inquiries

For inquiries and questions, we collect the inquiry or question, together with name, contact details (email address, phone number and mailing address) and any other additional information voluntarily submitted to us through a Contact Us form or an email. We use this information to address the inquiry and respond to the question.

### Online Store

For orders and purchases placed through our online store on this site, we collect order details, name, institution name and address (if applicable), email address, phone number, shipping and billing addresses, credit/debit card information, shipping options and any instructions. We use this information to complete transactions, fulfill orders, communicate with individuals placing orders or visiting the online store, and for related purposes.

### Surveys

Pearson may offer opportunities to provide feedback or participate in surveys, including surveys evaluating Pearson products, services or sites. Participation is voluntary. Pearson collects information requested in the survey questions and uses the information to evaluate, support, maintain and improve products, services or sites, develop new products and services, conduct educational research and for other purposes specified in the survey.

### Contests and Drawings

Occasionally, we may sponsor a contest or drawing. Participation is optional. Pearson collects name, contact information and other information specified on the entry form for the contest or drawing to conduct the contest or drawing. Pearson may collect additional personal information from the winners of a contest or drawing in order to award the prize and for tax reporting purposes, as required by law.

If you have elected to receive email newsletters or promotional mailings and special offers but want to unsubscribe, simply email information@informit.com.

### Service Announcements

On rare occasions it is necessary to send out a strictly service related announcement. For instance, if our service is temporarily suspended for maintenance we might send users an email. Generally, users may not opt-out of these communications, though they can deactivate their account information. However, these communications are not promotional in nature.

### Customer Service

We communicate with users on a regular basis to provide requested services and in regard to issues relating to their account we reply via email or phone in accordance with the users' wishes when a user submits their information through our Contact Us form.

## Other Collection and Use of Information

### Application and System Logs

Pearson automatically collects log data to help ensure the delivery, availability and security of this site. Log data may include technical information about how a user or visitor connected to this site, such as browser type, type of computer/device, operating system, internet service provider and IP address. We use this information for support purposes and to monitor the health of the site, identify problems, improve service, detect unauthorized access and fraudulent activity, prevent and respond to security incidents and appropriately scale computing resources.

### Web Analytics

Pearson may use third party web trend analytical services, including Google Analytics, to collect visitor information, such as IP addresses, browser types, referring pages, pages visited and time spent on a particular site. While these analytical services collect and report information on an anonymous basis, they may use cookies to gather web trend information. The information gathered may enable Pearson (but not the third party web trend services) to link information with application and system log data. Pearson uses this information for system administration and to identify problems, improve service, detect unauthorized access and fraudulent activity, prevent and respond to security incidents, appropriately scale computing resources and otherwise support and deliver this site and its services.

### Cookies and Related Technologies

This site uses cookies and similar technologies to personalize content, measure traffic patterns, control security, track use and access of information on this site, and provide interest-based messages and advertising. Users can manage and block the use of cookies through their browser. Disabling or blocking certain cookies may limit the functionality of this site.

### Do Not Track

This site currently does not respond to Do Not Track signals.

## Security

Pearson uses appropriate physical, administrative and technical security measures to protect personal information from unauthorized access, use and disclosure.

## Children

This site is not directed to children under the age of 13.

## Marketing

Pearson may send or direct marketing communications to users, provided that

• Pearson will not use personal information collected or processed as a K-12 school service provider for the purpose of directed or targeted advertising.
• Such marketing is consistent with applicable law and Pearson's legal obligations.
• Pearson will not knowingly direct or send marketing communications to an individual who has expressed a preference not to receive marketing.
• Where required by applicable law, express or implied consent to marketing exists and has not been withdrawn.

Pearson may provide personal information to a third party service provider on a restricted basis to provide marketing solely on behalf of Pearson or an affiliate or customer for whom Pearson is a service provider. Marketing preferences may be changed at any time.

## Correcting/Updating Personal Information

If a user's personally identifiable information changes (such as your postal address or email address), we provide a way to correct or update that user's personal data provided to us. This can be done on the Account page. If a user no longer desires our service and desires to delete his or her account, please contact us at customer-service@informit.com and we will process the deletion of a user's account.

## Choice/Opt-out

Users can always make an informed choice as to whether they should proceed with certain services offered by InformIT. If you choose to remove yourself from our mailing list(s) simply visit the following page and uncheck any communication you no longer want to receive: www.informit.com/u.aspx.

## Sale of Personal Information

Pearson does not rent or sell personal information in exchange for any payment of money.

While Pearson does not sell personal information, as defined in Nevada law, Nevada residents may email a request for no sale of their personal information to NevadaDesignatedRequest@pearson.com.

## Supplemental Privacy Statement for California Residents

California residents should read our Supplemental privacy statement for California residents in conjunction with this Privacy Notice. The Supplemental privacy statement for California residents explains Pearson's commitment to comply with California law and applies to personal information of California residents collected in connection with this site and the Services.

## Sharing and Disclosure

Pearson may disclose personal information, as follows:

• As required by law.
• With the consent of the individual (or their parent, if the individual is a minor)
• In response to a subpoena, court order or legal process, to the extent permitted or required by law
• To protect the security and safety of individuals, data, assets and systems, consistent with applicable law
• In connection the sale, joint venture or other transfer of some or all of its company or assets, subject to the provisions of this Privacy Notice
• To investigate or address actual or suspected fraud or other illegal activities
• To exercise its legal rights, including enforcement of the Terms of Use for this site or another contract
• To affiliated Pearson companies and other companies and organizations who perform work for Pearson and are obligated to protect the privacy of personal information consistent with this Privacy Notice
• To a school, organization, company or government agency, where Pearson collects or processes the personal information in a school setting or on behalf of such organization, company or government agency.

This web site contains links to other sites. Please be aware that we are not responsible for the privacy practices of such other sites. We encourage our users to be aware when they leave our site and to read the privacy statements of each and every web site that collects Personal Information. This privacy statement applies solely to information collected by this web site.